Defeating Doc Ock:-  Save all of the people on the train and complete the other levels until you get to the level where he recreates his machine. To complete this level you must destroy all of the power generators. To do this, follow the cord that is streaked with orange (or yellow) and black. You will then get to the generators. Just kick them to destroy them. His shield will then go away and you must take out all of his legs. However, be careful. Then to defeat him, keep punching and kicking away.

Defeating Mysterio:-  You first need to know which hologram is him. To do that, you look at the faces behind all of the holograms. The one that is smiling will have the real Mysterio directly in front of it. Do not touch him while the three fireballs are orbiting his head. When he tries to shoot you and no longer has them orbiting his head, go in and hit him. When the fireballs return, back off. Keep repeating this. Note: Do not forget about the other holograms; they are just as powerful.

Defeating Rhino:-  To defeat Rhino, all you have to do is jump. While you are in the air, press L. Then, wait for him to run into the wall and get some combos on him. When he runs into the next room, do the same. Run around the poles when he gets the big pipe.

Defeating Shocker:-  To defeat Shocker, you must let Rhino knock down the platform he is standing on (see the "Defeating Rhino" hint). Then, lock in on him with the Spidey target and either blind him or hold L and press Triangle. Keep doing that and try not to die.

Defeating Vulture:-  Stay in the construction area on top of the building. Remain in between the two buildings that Vulture cannot get to you. After awhile, his health will get down to green. He will land, and this is when you can attack him. Do it quickly; you only get five to ten seconds to punch him.

Passwords

Name Entry Cheats  -  You may only use these cheats with a memory card that has no previous Spider-Man 2 gamesaves on it. If you enter the code more than once in a row you will have 200000 more hero points than if you entered it once. So twice gives you 4000000, 3 times gives you 6000000, etc.

Password Effect  -  HCRAYERT You will have more than 40%, 21,000 Hero points with swing speed and Win Zip upgrades, and Big Game Hunter, Alien Buster, Shock Absorber.

How to Unlock
Endurance Rounds in Fight Arena Beat Timed Round 3
Fight Arena Beat the Final Doc Ock Battle
Movie Theatre Beat the Final Doc Ock Battle
Wallsprint Upgrade 2 Collect all 150 Secret Skyscraper Tokens

You can find these in your awards screen in the pause menu. There is a total of 40 awards.

Alien Buster Defeat Mysterio
Anger Manager Stop 25 road rages
Automobile Avenger Stop 25 car jackings
Bane of Petty Thieves Stop 25 purse snatchers
Big Game Hunter Defeat Rhino
Champ Defeat 200 enemies
Crime Stopper Stop 250 petty crimes
Drenched Explorer Collect all 130 Bouy Tokens
Employee of the Month Complete all Pizza Missions (20)
Friend to Children Return 25 balloons to children
Game Master Complete Everything in the game (100%)
Gold Medalist Beat all challenges' mega times
Good samaritan Help 250 citizens in distress
hardcore gamer Complete all arcade games, with top scores
Hero Accumulate 45K hero points
Hero in Training Accumulate 15K hero points
Honorary Deputy Assisted 25 officiers
Human Ambulance Resolve 25 medical emergencies
Knowledge Seeker Collect all 213 Hint Markers
Lifer Preserver Resolve 25 sinking boat crisises
Lifter of Spirits Rescue 25 hanging citizens
Lover not a Fighter Complete all Mary Jane Missions (10)
Master Explorer All exploration tokens found
Mega Champ Defeat 500 enemies
Mega Hero Accumulate 200K hero points
Partycrasher Stop 25 battle royals
Peace maker Prevent 25 gang wars
Shock Absorber Defeat Shocker
Shutterbug Complete all Daily Bugle Missions (6)
Silver Medalist Beat all challenges
Speed Freak Get max swing speed
Stick Up Artist Foil 25 robberies
Sucker Foil 25 ambushes
Superhero Accumulate 100K hero points
Tentacle Wrangler Defeat Doc Ock
Thug Mugger Prevent 25 muggings
Towering Explorer All skyscraper tokens found
Vigilant Explorer All hideout tokens found
Watch Dog Foil 25 break-ins
Watchful Explorer All secret tokens found

Army of Darkness/Evil Dead tribute  -  When fighting Mysterio and his flyign henchman in the theatre, save all 6 reporters before destroying all of his minions.

If you are successful, while you are fighting his villains, Mysterio will start to recite lines from Army of Darkness and Evil Dead, films also done by Spider-Man 2 director Sam Raimi.